I had this problem before I used firefox. I changed to ff a couple of weeks ago to try and cure it.
Ok, you have a LOT of pointless programs loading with windows, does it take ages to bootup?
I typically have 4 or 5 items, msn, antivirus, antispyware, firewall but little else is needed.
From the bottom you have:
adobe - unnecessary can untick
ms office - ditto
ususpm - windows installer updater, not needed but leave it as might be doing something
googletoolbar - unnecessary can untick
AOL - i assume you use (it's crap but leave it)
qttask- is quicktime untick
homerunner - is tomtom software, if you use it leave it
avgcc - is your antivirus, leave it
apdproxy - is adobe again, untick
jusched - java updater, untick cuz windows does this automatically
realplay - is similar, untick
dumprep - is to report errors to microsoft, not needed, untick
datalayer - is nokia software for pcsuite, if you use it often leave it, up to you
mpftray - is macafee security suite, leave it
AOLdial - self explanatory, leave if you use aol
fts - is for your broadband, leave it
qtzgacer - is acers config utility, not necessary but leave it
atiptaxx -is the ati logo in your systray, untick
tintsetp - is used for translating in ms programs, chinese etc in word etc. untick both
imscinst - as above
imjpmig - again for inputting/translating asian characters, untick
pdvdserv - is for a usb remote control for powerdvd, if you have one leave if not untick
syntpenh - is for the touchpad, leave it
syntplpr - as above
alaunch - diagnostics bundle for acer lappies, leave it
You can try these changes if you wish, they will not do any harm, they may not help your particular problem either though but it will bootup a lot quicker at least.
When you are done close th window click to reboot, then when rebooted click "do not show this message blah blah".
I notice no spyware program, i'd get one if i were you.