I've found this to usually be caused by faulty or incorrectly seated memory. Try removing the memory sticks and reseating them.
If it still happens try posting a picture of the BSOD screen so I can see the error codes. What BCCode does it show?
Ooh blimey can't remember, but if it happens again I will note everything down.
As I say, now the webcam is unplugged the pc is extremely quick. Total coincidence???
Small chance a bad USB driver for the webcam is causing memory to become corrupt. So when it's unplugged the driver doesn't get loaded.